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1 | US10879114B1 |
Conductive fill
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Publication/Patent Number: US10879114B1 | Publication Date: 2020-12-29 | Application Number: 16/549,256 | Filing Date: 2019-08-23 | Inventor: Wu, Jung-tang Liao, Chi-hung Wu, Szu-hua Ou yang liang yueh Lee, Chin-szu | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/4763 | Abstract: A conductive fill is provided in an opening of an interconnect layer. A seed layer is formed, a portion of which is then oxidized. The oxygen is removed in a treatment process and the surface of the de-oxidized seed layer is hydrolyzed to form a hydroxyl sublayer and moisturized. The conductive fill is formed over the hydroxyl sublayer. | |||
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2 | US10867845B2 |
Semiconductor device and method
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Publication/Patent Number: US10867845B2 | Publication Date: 2020-12-15 | Application Number: 16/599,940 | Filing Date: 2019-10-11 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Su, Ching-hwanq Ou yang liang yueh Tsai, Ming-hsing Lin, Yu-ting | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming a first opening in a dielectric layer over a substrate, lining sidewalls and a bottom of the first opening with a conductive barrier layer, and depositing a seed layer over the conductive barrier layer. The method further includes treating the seed layer with a plasma process, and filling the first opening with a conductive material after the treating the seed layer. | |||
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3 | US10636702B2 |
Conductive interconnect structures in integrated circuits
|
Publication/Patent Number: US10636702B2 | Publication Date: 2020-04-28 | Application Number: 16/178,470 | Filing Date: 2018-11-01 | Inventor: Wu, Jung-tang Lien, Shao Tzu Liao, Chi-hung Wu, Szu-hua Ou yang liang yueh Lee, Chin-szu | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/4763 | Abstract: An interconnect structure and a method of forming the interconnect structure are provided. A dielectric layer and openings therein are formed over a substrate. A conductive seed layer is formed over the top surface and along a bottom and sidewalls of the openings. A conductive fill layer is formed over the seed layer. Metal oxide on the surface of the seed layer may be reduced/removed by a surface pre-treatment. The cleaned surface is covered by depositing fill material over the seed layer without exposing the surface to oxygen. The surface treatment may include a reactive remote plasma clean using hydrogen radicals. If electroplating is used to deposit the fill layer, then the surface treatment may include soaking the substrate in the electrolyte before turning on the electroplating current. Other surface treatments may include active pre-clean (APC) using hydrogen radicals; or Ar sputtering using a metal clean version xT (MCxT) tool. | |||
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4 | US202043781A1 |
Semiconductor Device and Method
|
Publication/Patent Number: US202043781A1 | Publication Date: 2020-02-06 | Application Number: 20/191,659 | Filing Date: 2019-10-11 | Inventor: Tsai, Ming-hsing Wang, Yu-sheng Hung, Chi-cheng Su, Ching-hwanq Lin, Yu-ting Ou yang liang yueh | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L29/66 | Abstract: A method includes forming a first opening in a dielectric layer over a substrate, lining sidewalls and a bottom of the first opening with a conductive barrier layer, and depositing a seed layer over the conductive barrier layer. The method further includes treating the seed layer with a plasma process, and filling the first opening with a conductive material after the treating the seed layer. | |||
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5 | US2020075407A1 |
Methods for Forming Contact Plugs with Reduced Corrosion
|
Publication/Patent Number: US2020075407A1 | Publication Date: 2020-03-05 | Application Number: 16/678,410 | Filing Date: 2019-11-08 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Kao, Chen-yuan Chiu, Yi-wei Ou yang liang yueh Pai, Yueh-ching | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming an ILD to cover a gate stack of a transistor. The ILD and the gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a source/drain region of the transistor or a gate electrode in the gate stack is exposed through the contact opening. A conductive capping layer is formed to extend into the contact opening. A metal-containing material is plated on the conductive capping layer in a plating solution using electrochemical plating. The metal-containing material has a portion filling the contact opening. The plating solution has a sulfur content lower than about 100 ppm. A planarization is performed on the wafer to remove excess portions of the metal-containing material. A remaining portion of the metal-containing material and a remaining portion of the conductive capping layer in combination form a contact plug. | |||
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6 | US2020105593A1 |
Conductive Interconnect Structures in Integrated Circuits
|
Publication/Patent Number: US2020105593A1 | Publication Date: 2020-04-02 | Application Number: 16/178,470 | Filing Date: 2018-11-01 | Inventor: Wu, Jung-tang Lien, Shao Tzu Liao, Chi-hung Wu, Szu-hua Ou yang liang yueh Lee, Chin-szu | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: An interconnect structure and a method of forming the interconnect structure are provided. A dielectric layer and openings therein are formed over a substrate. A conductive seed layer is formed over the top surface and along a bottom and sidewalls of the openings. A conductive fill layer is formed over the seed layer. Metal oxide on the surface of the seed layer may be reduced/removed by a surface pre-treatment. The cleaned surface is covered by depositing fill material over the seed layer without exposing the surface to oxygen. The surface treatment may include a reactive remote plasma clean using hydrogen radicals. If electroplating is used to deposit the fill layer, then the surface treatment may include soaking the substrate in the electrolyte before turning on the electroplating current. Other surface treatments may include active pre-clean (APC) using hydrogen radicals; or Ar sputtering using a metal clean version xT (MCxT) tool. | |||
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7 | US2020043781A1 |
Semiconductor Device and Method
|
Publication/Patent Number: US2020043781A1 | Publication Date: 2020-02-06 | Application Number: 16/599,940 | Filing Date: 2019-10-11 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Su, Ching-hwanq Ou yang liang yueh Tsai, Ming-hsing Lin, Yu-ting | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming a first opening in a dielectric layer over a substrate, lining sidewalls and a bottom of the first opening with a conductive barrier layer, and depositing a seed layer over the conductive barrier layer. The method further includes treating the seed layer with a plasma process, and filling the first opening with a conductive material after the treating the seed layer. | |||
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8 | US2020258777A1 |
Conductive Interconnect Structures in Integrated Circuits
|
Publication/Patent Number: US2020258777A1 | Publication Date: 2020-08-13 | Application Number: 16/858,838 | Filing Date: 2020-04-27 | Inventor: Wu, Jung-tang Lien, Shao Tzu Liao, Chi-hung Wu, Szu-hua Ou yang liang yueh Lee, Chin-szu | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: An interconnect structure and a method of forming the interconnect structure are provided. A dielectric layer and openings therein are formed over a substrate. A conductive seed layer is formed over the top surface and along a bottom and sidewalls of the openings. A conductive fill layer is formed over the seed layer. Metal oxide on the surface of the seed layer may be reduced/removed by a surface pre-treatment. The cleaned surface is covered by depositing fill material over the seed layer without exposing the surface to oxygen. The surface treatment may include a reactive remote plasma clean using hydrogen radicals. If electroplating is used to deposit the fill layer, then the surface treatment may include soaking the substrate in the electrolyte before turning on the electroplating current. Other surface treatments may include active pre-clean (APC) using hydrogen radicals; or Ar sputtering using a metal clean version xT (MCxT) tool. | |||
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9 | US10872815B2 |
Conductive interconnect structures in integrated circuits
|
Publication/Patent Number: US10872815B2 | Publication Date: 2020-12-22 | Application Number: 16/858,838 | Filing Date: 2020-04-27 | Inventor: Wu, Jung-tang Lien, Shao Tzu Liao, Chi-hung Wu, Szu-hua Ou yang liang yueh Lee, Chin-szu | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/4763 | Abstract: An interconnect structure and a method of forming the interconnect structure are provided. A dielectric layer and openings therein are formed over a substrate. A conductive seed layer is formed over the top surface and along a bottom and sidewalls of the openings. A conductive fill layer is formed over the seed layer. Metal oxide on the surface of the seed layer may be reduced/removed by a surface pre-treatment. The cleaned surface is covered by depositing fill material over the seed layer without exposing the surface to oxygen. The surface treatment may include a reactive remote plasma clean using hydrogen radicals. If electroplating is used to deposit the fill layer, then the surface treatment may include soaking the substrate in the electrolyte before turning on the electroplating current. Other surface treatments may include active pre-clean (APC) using hydrogen radicals; or Ar sputtering using a metal clean version xT (MCxT) tool. | |||
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10 | TWI669784B |
Methods for forming contact plugs
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Publication/Patent Number: TWI669784B | Publication Date: 2019-08-21 | Application Number: 106135929 | Filing Date: 2017-10-19 | Inventor: Wang, Yu Sheng Chiu, Yi Wei Hung, Chi Cheng Kao, Chen Yuan Pai, Yueh Ching Ou, Yang Liang Yueh | Assignee: Taiwan Semiconductor Manufacturing Co., Ltd. | IPC: H01L21/768 | Abstract: A method includes forming an ILD to cover a gate stack of a transistor. The ILD and the gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a source/drain region of the transistor or a gate electrode in the gate stack is exposed through the contact opening. A conductive capping layer is formed to extend into the contact opening. A metal-containing material is plated on the conductive capping layer in a plating solution using electrochemical plating. The metal-containing material has a portion filling the contact opening. The plating solution has a sulfur content lower than about 100 ppm. A planarization is performed on the wafer to remove excess portions of the metal-containing material. A remaining portion of the metal-containing material and a remaining portion of the conductive capping layer in combination form a contact plug. | |||
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11 | KR102030242B1 |
METHODS FOR FORMING CONTACT PLUGS WITH REDUCED CORROSION
|
Publication/Patent Number: KR102030242B1 | Publication Date: 2019-10-10 | Application Number: 20170121446 | Filing Date: 2017-09-20 | Inventor: Kao, Chen Yuan Pai, Yueh Ching Hung, Chi Cheng Ou, Yang Liang Yueh Chiu, Yi Wei Wang, Yu Sheng | Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD. | IPC: H01L21/768 | Abstract: A method comprises a step of forming an ILD to cover a gate stack of a transistor, wherein the ILD and gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a gate electrode in a source/drain region of the transistor or the gate stack is exposed through the contact opening. A conductive cover layer is formed to extend into the contact opening, and a metal-containing material is plated on the conductive cover layer in a plating solution by using electrochemical plating, wherein the metal-containing material has a part that fills the contact opening. The plating solution has sulfur content less than about 100 ppm, and planarization is performed on the wafer to remove excess parts of the metal-containing material. In addition, residual parts of the metal-containing material and residual parts of the conductive cover layer are combined to form contact plugs. | |||
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12 | US10186456B2 |
Methods for forming contact plugs with reduced corrosion
|
Publication/Patent Number: US10186456B2 | Publication Date: 2019-01-22 | Application Number: 15/492,113 | Filing Date: 2017-04-20 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Kao, Chen-yuan Chiu, Yi-wei Ou yang liang yueh Pai, Yueh-ching | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming an ILD to cover a gate stack of a transistor. The ILD and the gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a source/drain region of the transistor or a gate electrode in the gate stack is exposed through the contact opening. A conductive capping layer is formed to extend into the contact opening. A metal-containing material is plated on the conductive capping layer in a plating solution using electrochemical plating. The metal-containing material has a portion filling the contact opening. The plating solution has a sulfur content lower than about 100 ppm. A planarization is performed on the wafer to remove excess portions of the metal-containing material. A remaining portion of the metal-containing material and a remaining portion of the conductive capping layer in combination form a contact plug. | |||
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13 | US10483165B2 |
Methods for forming contact plugs with reduced corrosion
|
Publication/Patent Number: US10483165B2 | Publication Date: 2019-11-19 | Application Number: 16/213,326 | Filing Date: 2018-12-07 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Kao, Chen-yuan Chiu, Yi-wei Ou yang liang yueh Pai, Yueh-ching | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L29/78 | Abstract: A method includes forming an ILD to cover a gate stack of a transistor. The ILD and the gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a source/drain region of the transistor or a gate electrode in the gate stack is exposed through the contact opening. A conductive capping layer is formed to extend into the contact opening. A metal-containing material is plated on the conductive capping layer in a plating solution using electrochemical plating. The metal-containing material has a portion filling the contact opening. The plating solution has a sulfur content lower than about 100 ppm. A planarization is performed on the wafer to remove excess portions of the metal-containing material. A remaining portion of the metal-containing material and a remaining portion of the conductive capping layer in combination form a contact plug. | |||
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14 | US2019109043A1 |
Semiconductor Device and Method
|
Publication/Patent Number: US2019109043A1 | Publication Date: 2019-04-11 | Application Number: 16/213,868 | Filing Date: 2018-12-07 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Su, Ching-hwanq Ou yang liang yueh Tsai, Ming-hsing Lin, Yu-ting | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming a first opening in a dielectric layer over a substrate, lining sidewalls and a bottom of the first opening with a conductive barrier layer, and depositing a seed layer over the conductive barrier layer. The method further includes treating the seed layer with a plasma process, and filling the first opening with a conductive material after the treating the seed layer. | |||
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15 | US10497615B2 |
Semiconductor device and method
|
Publication/Patent Number: US10497615B2 | Publication Date: 2019-12-03 | Application Number: 16/213,868 | Filing Date: 2018-12-07 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Su, Ching-hwanq Ou yang liang yueh Tsai, Ming-hsing Lin, Yu-ting | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming a first opening in a dielectric layer over a substrate, lining sidewalls and a bottom of the first opening with a conductive barrier layer, and depositing a seed layer over the conductive barrier layer. The method further includes treating the seed layer with a plasma process, and filling the first opening with a conductive material after the treating the seed layer. | |||
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16 | US2019115256A1 |
Methods for Forming Contact Plugs with Reduced Corrosion
|
Publication/Patent Number: US2019115256A1 | Publication Date: 2019-04-18 | Application Number: 16/213,326 | Filing Date: 2018-12-07 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Kao, Chen-yuan Chiu, Yi-wei Ou yang liang yueh Pai, Yueh-ching | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming an ILD to cover a gate stack of a transistor. The ILD and the gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a source/drain region of the transistor or a gate electrode in the gate stack is exposed through the contact opening. A conductive capping layer is formed to extend into the contact opening. A metal-containing material is plated on the conductive capping layer in a plating solution using electrochemical plating. The metal-containing material has a portion filling the contact opening. The plating solution has a sulfur content lower than about 100 ppm. A planarization is performed on the wafer to remove excess portions of the metal-containing material. A remaining portion of the metal-containing material and a remaining portion of the conductive capping layer in combination form a contact plug. | |||
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17 | KR20180118031A |
METHODS FOR FORMING CONTACT PLUGS WITH REDUCED CORROSION
|
Publication/Patent Number: KR20180118031A | Publication Date: 2018-10-30 | Application Number: 20170121446 | Filing Date: 2017-09-20 | Inventor: Kao, Chen Yuan Pai, Yueh Ching Hung, Chi Cheng Ou, Yang Liang Yueh Chiu, Yi Wei Wang, Yu Sheng | Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD. | IPC: H01L21/768 | Abstract: A method comprises a step of forming an ILD to cover a gate stack of a transistor, wherein the ILD and gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a gate electrode in a source/drain region of the transistor or the gate stack is exposed through the contact opening. A conductive cover layer is formed to extend into the contact opening, and a metal-containing material is plated on the conductive cover layer in a plating solution by using electrochemical plating, wherein the metal-containing material has a part that fills the contact opening. The plating solution has sulfur content less than about 100 ppm, and planarization is performed on the wafer to remove excess parts of the metal-containing material. In addition, residual parts of the metal-containing material and residual parts of the conductive cover layer are combined to form contact plugs. | |||
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18 | TW201839911A |
Methods for forming contact plugs
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Publication/Patent Number: TW201839911A | Publication Date: 2018-11-01 | Application Number: 106135929 | Filing Date: 2017-10-19 | Inventor: Wang, Yu Sheng Chiu, Yi Wei Hung, Chi Cheng Kao, Chen Yuan Pai, Yueh Ching Ou, Yang Liang Yueh | Assignee: Taiwan Semiconductor Manufacturing Co., Ltd. | IPC: H01L21/768 | Abstract: A method includes forming an ILD to cover a gate stack of a transistor. The ILD and the gate stack are parts of a wafer. The ILD is etched to form a contact opening, and a source/drain region of the transistor or a gate electrode in the gate stack is exposed through the contact opening. A conductive capping layer is formed to extend into the contact opening. A metal-containing material is plated on the conductive capping layer in a plating solution using electrochemical plating. The metal-containing material has a portion filling the contact opening. The plating solution has a sulfur content lower than about 100 ppm. A planarization is performed on the wafer to remove excess portions of the metal-containing material. A remaining portion of the metal-containing material and a remaining portion of the conductive capping layer in combination form a contact plug. | |||
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19 | KR20180121826A |
SEMICONDUCTOR DEVICE AND METHOD
|
Publication/Patent Number: KR20180121826A | Publication Date: 2018-11-09 | Application Number: 20170166505 | Filing Date: 2017-12-06 | Inventor: Hung, Chi Cheng Ou, Yang Liang Yueh Su, Ching Hwanq Wang, Yu Sheng Lin, Yu Ting Tsai, Ming Hsing | Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD. | IPC: H01L21/768 | Abstract: A method capable of processing a small feature size includes the steps of: forming a first opening in a dielectric layer over a substrate; lining sidewalls and the bottom of the first opening with a conductive barrier layer; and depositing a seed layer over the conductive barrier layer. The method further includes: treating the seed layer with a plasma process; and filling the first opening with a conductive material after treating the seed layer. | |||
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20 | US2018315647A1 |
Semiconductor Device and Method
|
Publication/Patent Number: US2018315647A1 | Publication Date: 2018-11-01 | Application Number: 15/583,789 | Filing Date: 2017-05-01 | Inventor: Wang, Yu-sheng Hung, Chi-cheng Su, Ching-hwanq Ou yang liang yueh Tsai, Ming-hsing Lin, Yu-ting | Assignee: Taiwan Semiconductor Manufacturing Company, Ltd. | IPC: H01L21/768 | Abstract: A method includes forming a first opening in a dielectric layer over a substrate, lining sidewalls and a bottom of the first opening with a conductive barrier layer, and depositing a seed layer over the conductive barrier layer. The method further includes treating the seed layer with a plasma process, and filling the first opening with a conductive material after the treating the seed layer. |