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1
US20170088653A1
Publication/Patent Number: US20170088653A1
Publication date: 2017-03-30
Application number: 15/377,549
Filing date: 2016-12-13
Abstract: Provided is a surfactant which has a high surface tension reducing ability and a high solubility in a liquid medium, containing a fluorine-containing copolymer containing, as essential components, a monomer having a fluoroalkyl group having 1 to 7 carbon atoms, a hydrophilic monomer, and a monomer having an ion donor group. Further provided are a coating composition, an ink composition and a photographic emulsion composition, each comprising the surfactant. Provided is a surfactant which has a high surface tension reducing ability and a high solubility in a liquid medium, containing a fluorine-containing copolymer containing, as essential components, a monomer having a fluoroalkyl group having 1 to 7 carbon atoms, a hydrophilic ...more ...less
2
CA2867281C
Publication/Patent Number: CA2867281C
Publication date: 2017-07-04
Application number: 2867281
Filing date: 2013-03-14
Abstract: Provided is a water-resistant/oil-resistant agent for paper that exhibits little foam formation and excellent product stability. The water-resistant/oil-resistant agent for paper comprises: (1) (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1) (General formula (1): CH2=C(-X)-C(=O)-Y-Z-Rf Provided is a water-resistant/oil-resistant agent for paper that exhibits little foam formation and excellent product stability. The water-resistant/oil-resistant agent for paper comprises: (1) (a) a fluorine-containing monomer that has a fluoroalkyl group and that is ...more ...less
3
US9540470B2
Publication/Patent Number: US9540470B2
Publication date: 2017-01-10
Application number: 13/390,758
Filing date: 2010-08-17
Abstract: Disclosed is a treatment agent for paper comprising a fluorine-containing copolymer having a repeat unit (a) derived from a fluorine-containing monomer represented by general formula (I): CH2═C(—X)—C(═O)—Y—[—CH2)m—Z—]p—(CH2)n—Rf; a repeat unit (b) derived from at least one amino monomer represented by general formula (II-1): or a derivative thereof; and a repeat unit (c) derived from a pyrrolidone monomer represented by general formula (III): The treatment agent for paper provides paper having high oil resistance and high water resistance. Disclosed is a treatment agent for paper comprising a fluorine-containing copolymer having a repeat unit (a) derived from a fluorine-containing monomer represented by general formula (I): ...more ...less
4
CN102365340B
Publication/Patent Number: CN102365340B
Publication date: 2016-05-04
Application number: 201080013972
Filing date: 2010-03-24
Abstract: Provided is a surfactant which has a high surface tension reducing ability and a high solubility in a liquid medium
5
US9464384B2
Publication/Patent Number: US9464384B2
Publication date: 2016-10-11
Application number: 14/385,333
Filing date: 2013-03-14
Abstract: A water-resistant/oil-resistant agent for paper containing (I) a fluorine-containing copolymer including repeating units derived from: (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1): CH2═C(—X)—C(═O)—Y—Z—Rf (where X is a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or the like; Y is —O— or —NH—; Z is an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-10 carbon atoms, a cycloaliphatic group, or the like; and Rf is a linear or branched fluoroalkyl group having 1-6 carbon atoms), and (b) a (meth)acrylate monomer containing no fluorine atoms; and (II) a polypropylene glycol compound. Also disclosed is a method for treating paper, a treated paper and a composition for treating paper containing the water-resistant/oil resistant agent. A water-resistant/oil-resistant agent for paper containing (I) a fluorine-containing copolymer including repeating units derived from: (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1): ...more ...less
6
US9249540B2
Publication/Patent Number: US9249540B2
Publication date: 2016-02-02
Application number: 13/393,431
Filing date: 2010-08-31
Abstract: Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1-6 carbon atoms, hydrophilic monomer, and monomer having an anion-donating group, which agent affords a superior water and oil resistance to a paper. The invention also discloses a process for treating a paper by the water and oil resistant agent and a treated paper thereby. Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1-6 carbon atoms, hydrophilic monomer, and monomer having an anion-donating group, which agent ...more ...less
7
EP2536772B1
Publication/Patent Number: EP2536772B1
Publication date: 2016-02-10
Application number: 11723134.0
Filing date: 2011-02-14
8
ES2563205T3
Publication/Patent Number: ES2563205T3
Publication date: 2016-03-11
Application number: 11723134
Filing date: 2011-02-14
Abstract: Un agente
9
EP2473673B1
Publication/Patent Number: EP2473673B1
Publication date: 2016-12-21
Application number: 10755005.5
Filing date: 2010-08-31
10
EP2826918A1
Publication/Patent Number: EP2826918A1
Publication date: 2015-01-21
Application number: 13761072.1
Filing date: 2013-03-14
Abstract: Provided is a water-resistant/oil-resistant agent for paper that exhibits little foam formation and excellent product stability. The water-resistant/oil-resistant agent for paper comprises: (I) (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1) (General formula (1): CH2=C(-X)-C(=O)-Y-Z-Rf [In the formula, X is a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or the like. Y is -O- or -NH-. Z is an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-10 carbon atoms, a cycloaliphatic group, or the like. Rf is a linear or branched fluoroalkyl group having 1-6 carbon atoms.]) and (b) a fluorine-containing copolymer that includes, as a necessary component, a repeating unit derived from a (meth)acrylate monomer containing no fluorine atoms; and (II) a polypropylene glycol compound. Provided is a water-resistant/oil-resistant agent for paper that exhibits little foam formation and excellent product stability. The water-resistant/oil-resistant agent for paper comprises: (I) (a) a fluorine-containing monomer that has a fluoroalkyl group and that is ...more ...less
11
US20150096699A1
Publication/Patent Number: US20150096699A1
Publication date: 2015-04-09
Application number: 14/385,333
Filing date: 2013-03-14
Abstract: A water-resistant/oil-resistant agent for paper containing (I) a fluorine-containing copolymer including repeating units derived from: (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1): CH2═C(—X)—C(═O)—Y—Z—Rf (where X is a hydrogen atom, a linear or branched alkyl group having 1-21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or the like; Y is —O— or —NH—; Z is an aliphatic group having 1-10 carbon atoms, an aromatic group having 6-10 carbon atoms, a cycloaliphatic group, or the like; and Rf is a linear or branched fluoroalkyl group having 1-6 carbon atoms), and (b) a (meth)acrylate monomer containing no fluorine atoms; and (II) a polypropylene glycol compound. Also disclosed is a method for treating paper, a treated paper and a composition for treating paper containing the water-resistant/oil resistant agent. A water-resistant/oil-resistant agent for paper containing (I) a fluorine-containing copolymer including repeating units derived from: (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1): ...more ...less
12
EP2826918A4
Publication/Patent Number: EP2826918A4
Publication date: 2015-08-12
Application number: 13761072
Filing date: 2013-03-14
Abstract: Provided is a water-resistant/oil-resistant agent for paper that exhibits little foam formation and excellent product stability. The water-resistant/oil-resistant agent for paper comprises: (I) (a) a fluorine-containing monomer that has a fluoroalkyl group and that is represented by general formula (1) (General formula (1): CH 2 =C(-X)-C(=O)-Y-Z-Rf [In the formula Provided is a water-resistant/oil-resistant agent for paper that exhibits little foam formation and excellent product stability. The water-resistant/oil-resistant agent for paper comprises: (I) (a) a fluorine-containing monomer that has a fluoroalkyl group and that is ...more ...less
13
CA2771339C
Publication/Patent Number: CA2771339C
Publication date: 2015-03-10
Application number: 2771339
Filing date: 2010-08-31
Abstract: The present invention is directed to a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1 - 6 carbon atoms
14
ES2527829T3
Publication/Patent Number: ES2527829T3
Publication date: 2015-01-30
Application number: 10809960
Filing date: 2010-08-17
Abstract: Un copolímero
15
CN102471419B
Publication/Patent Number: CN102471419B
Publication date: 2015-04-29
Application number: 201080036059
Filing date: 2010-08-17
Abstract: Disclosed is a treatment agent for paper comprising a fluorine-containing copolymer having a repeat unit (a) derived from a fluorine-containing monomer represented by general formula (I): CH2=C(-X)-C(=O)-Y-[-(CH2)m-Z-]p-(CH2)n-Rf; a repeat unit (b) derived from at least one amino monomer represented by general formula (II-1) or a derivative thereof; and a repeat unit (c) derived from a pyrrolidone monomer represented by general formula (III). The treatment agent for paper provides paper having high oil resistance and high water resistance. Disclosed is a treatment agent for paper comprising a fluorine-containing copolymer having a repeat unit (a) derived from a fluorine-containing monomer represented by general formula (I): CH2=C(-X)-C(=O)-Y-[-(CH2)m-Z-]p-(CH2)n-Rf; a repeat unit (b) derived from at least one ...more ...less
16
US8992733B2
Publication/Patent Number: US8992733B2
Publication date: 2015-03-31
Application number: 13/578,957
Filing date: 2011-02-14
Abstract: Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1 to 6 carbon atoms, the agent being able to afford a superior water and oil resistance to a paper. The invention also discloses a composition comprising the water and oil resistant agent, a process for treating a paper thereby and a treated paper thereby. Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1 to 6 carbon atoms, the agent being able to afford a superior water and oil resistance to a paper ...more ...less
17
CA2771415C
Publication/Patent Number: CA2771415C
Publication date: 2015-04-14
Application number: 2771415
Filing date: 2010-08-17
Abstract: Disclosed is a treatment agent for paper comprising a fluorine-containing copolymer having a repeat unit (a) derived from a fluorine-containing monomer represented by general formula (I): CH2=C(-X)-C(=O)-Y-[-(CH2)m-Z-]p-(CH2)n-Rf; a repeat unit (b) derived from at least one amino monomer represented by general formula (II-1): (see formula II-1) or a derivative thereof; and a repeat unit (c) derived from a pyrrolidone monomer represented by general formula (III): ( see formula III) The treatment agent for paper provides paper having high oil resistance and high water resistance. Disclosed is a treatment agent for paper comprising a fluorine-containing copolymer having a repeat unit (a) derived from a fluorine-containing monomer represented by general formula (I): CH2=C(-X)-C(=O)-Y-[-(CH2)m-Z-]p-(CH2)n-Rf; a repeat unit (b) derived from at least one ...more ...less
18
CN102575435B
Publication/Patent Number: CN102575435B
Publication date: 2015-11-25
Application number: 201080038806
Filing date: 2010-08-31
Abstract: Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a fluoroalkyl group having 1 - 6 carbon atoms
19
CA2787833C
Publication/Patent Number: CA2787833C
Publication date: 2015-04-28
Application number: 2787833
Filing date: 2011-02-14
Abstract: Disclosed is a water and oil resistant agent comprising a fluorine-containing copolymer obtained by copolymerizing a (meth)acrylate monomer having a polyfluoroalkyl group having 1 to 6 carbon atoms
20
EP2270058B1
Publication/Patent Number: EP2270058B1
Publication date: 2015-08-19
Application number: 09726483.2
Filing date: 2009-03-27
Abstract: Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general formula (I) CH 2 =C(-X)-C(=O)-Y-[-(CH 2 ) m -Z-] p -(CH2) n -Rf (wherein X represents a hydrogen atom; Y represents -O- or -NH-; Z represents a direct bond, -S- or -SO 2 -; Rf represents a fluoroalkyl group having 1-6 carbon atoms; m is a number of 1-10; n is a number of 0-10; and p is 0 or 1) and (b) an alkoxy group-containing monomer represented by general formula (II) CH 2 =C(X')-C(=O)-O-(RO) q -H (wherein X' represents a hydrogen atom or a methyl group; R represents an alkylene group having 2-4 carbon atoms wherein a part or all of hydrogen atoms may be substituted by a hydroxyl group; and q represent an integer of 1-50). The fluorine-containing polymer does not contain a monomer having an amino group. Disclosed is a fluorine-containing copolymer having sufficient stability in water, which is capable of providing paper with sufficient oil resistance. The fluorine-containing polymer contains, as essential components, (a) a fluorine-containing monomer represented by general ...more ...less